METATHESIS OF FUNCTIONALIZED OLEFINS WITH WCL6- (OR WOCL4-) 1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE CATALYST

被引：11

作者：

BESPALOVA, NB

BOVINA, MA

机构：

[1] A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912 Moscow, Leninsky pr.

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 76卷 / 1-3期

关键词：

Catalysis;

D O I：

10.1016/0304-5102(92)80156-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several homogeneous and heterogeneous catalysts have been used for the metathesis of functionalized olefins. The homogeneous catalyst WCl6- (or WOCl4-) 1,1,3,3-tetramethyl-1,3-disilacyclobutane allows the metathesis of various functionalized olefins with short chain length (esters of fatty acids, unsaturated nitriles, etc.). Self- and co-metathesis of allyl cyanide, ethyl 4-pentenoate and allyltrimethylsilane with linear and cyclic olefins occurs with high yields and selectivity. These reactions allow the production of silyl derivatives of unsaturated nitriles and esters by single-step reactions.

引用

页码：181 / 187

页数：7

共 19 条

[1] BABICH ED, 1976, IAN SSSR KH, P2609
[2] OLEFIN METATHESIS OF ALKENYLSILANES .2. ON THE INITIATION OF OLEFIN METATHESIS WITH ORGANOSILANES
BERGLUND, M
ANDERSSON, C
LARSSON, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (1-2) : 61 - 73
[3] BESPALOVA NB, 1988, IAN SSSR KH, P920
[4] BESPALOVA NB, 1990, IAN SSSR KH, P172
[5] METATHESIS OF UNSATURATED NITRILES
BOSMA, RHA
VANDENAARDWEG, GCN
MOL, JC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (01) : 115 - 122
[6] BOSMA RHA, 1983, J CHEM SOC CHEM COMM, P262
[7] INFLUENCE OF BASICITY AND STERIC EFFECTS ON THE METATHESIS OF OLEFINIC AMINES
EDWIGE, C
LATTES, A
LAVAL, JP
MUTIN, R
BASSET, JM
NOUGUIER, R
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1980, 8 (1-3): : 297 - 311
[8] A NEW CATALYTIC-SYSTEM FOR THE METATHESIS OF FUNCTIONALIZED OLEFINS
LEVISALLES, J
RUDLER, H
CUZIN, D
RULL, T
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 26 (02): : 231 - 238
[9] METATHESIS OF FUNCTIONALIZED ACYCLIC OLEFINS
MOL, JC
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 65 (1-2): : 145 - 162
[10] METATHESIS OF FUNCTIONALIZED OLEFINS
MOL, JC
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1982, 15 (1-2): : 35 - 45

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