基于赤铁矿的生物质化学链燃烧过程中氮氧化物的释放特性

被引：5

作者：

肖申

沈来宏

肖军

牛欣

顾海明

宋涛

机构：

[1] 东南大学能源热转换及其过程测控教育部重点实验室

来源：

燃料化学学报 | 2015年 / 43卷 / 04期

关键词：

化学链燃烧; 生物质; 赤铁矿; 氮氧化物;

D O I：

暂无

中图分类号：

TK6 [生物能及其利用];

学科分类号：

080703 ;

摘要：

在单批次进料固定床上,基于赤铁矿载氧体,研究了还原反应阶段反应温度和水蒸气量对谷壳的氮氧化物释放特性的影响。研究表明,碳转化率随反应温度升高而增加,但随水蒸气量呈先增加后下降,并在水蒸气量为1.0 g/min时达到最大值。在实验条件下,还原阶段未检测到NO2。随着反应温度由750℃升高到900℃,NO的生成率增加,而N2O的生成率先增加后降低,在850℃时达到最大值。水蒸气量由0.5 g/min升高到2.0 g/min,N2O和NO的生成率均增加,且NO增加速率高于N2O。在反应后的载氧体中,检测到KAl Si3O8存在,表明载氧体与生物质中的K元素发生反应。

引用

页码：490 / 498

页数：9

共 21 条

[1]

NO release during chemical looping combustion with iron ore as an oxygen carrier.[J].Haiming Gu;Laihong Shen;Zhaoping Zhong;Xin Niu;Huijun Ge;Yufei Zhou;Shen Xiao;Shouxi Jiang.Chemical Engineering Journal.2015,

[2]

Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review.[J].Prakash Parthasarathy;K. Sheeba Narayanan.Renewable Energy.2014,

[3]

Biomass combustion in a CLC system using an iron ore as an oxygen carrier.[J].T. Mendiara;A. Abad;L.F. de Diego;F. García-Labiano;P. Gayán;J. Adánez.International Journal of Greenhouse Gas Control.2013,

[4]

Nitrogen transfer of fuel-N in chemical looping combustion.[J].Tao Song;Laihong Shen;Jun Xiao;Dingqian Chen;Haiming Gu;Siwen Zhang.Combustion and Flame.2011, 3

[5]

Gasification inhibition in chemical-looping combustion with solid fuels.[J].Martin Keller;Henrik Leion;Tobias Mattisson;Anders Lyngfelt.Combustion and Flame.2010, 3

[6]

Design and operation of a 10<ce:hsp sp="0.25"/>kW th chemical-looping combustor for solid fuels – Testing with South African coal.[J].Nicolas Berguerand;Anders Lyngfelt.Fuel.2008, 12

[7]

Experiments on chemical looping combustion of coal with a NiO based oxygen carrier.[J].Laihong Shen;Jiahua Wu;Jun Xiao.Combustion and Flame.2008, 3

[8]

The use of ilmenite as an oxygen carrier in chemical-looping combustion.[J].Henrik Leion;Anders Lyngfelt;Marcus Johansson;Erik Jerndal;Tobias Mattisson.Chemical Engineering Research and Design.2008, 9

[9]

The use of petroleum coke as fuel in a 10<ce:hsp sp="0.25"/>kW th chemical-looping combustor.[J].Nicolas Berguerand;Anders Lyngfelt.International Journal of Greenhouse Gas Control.2007, 2

[10]

Solid fuels in chemical-looping combustion.[J].Henrik Leion;Tobias Mattisson;Anders Lyngfelt.International Journal of Greenhouse Gas Control.2007, 2

← 1 2 3 →