Highly Efficient, Iodine-Free Dye-Sensitized Solar Cells with Solid-State Synthesis of Conducting Polymers

被引:183
作者
Koh, Jong Kwan [1 ]
Kim, Jeonghun [1 ]
Kim, Byeonggwan [1 ]
Kim, Jong Hak [1 ]
Kim, Eunkyoung [1 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
TITANIUM-DIOXIDE FILMS; CHARGE RECOMBINATION; HOLE CONDUCTORS; MESOPOROUS TIO2; NANOCRYSTALLINE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); ELECTROLYTE; KINETICS; ANIONS; OXIDE;
D O I
10.1002/adma.201004715
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solid-state polymerizable conductive monomer with good conductivity and penetration to the photoelectrode is introduced to iodine-free, solid-state dye-sensitized solar cells (DSSCs) using an easily accessible and widely applicable fabrication method. A conducting polymer as a hole transporting material effectively penetrates into the TiO2 pores and polymerizes with heating to mild temperatures. The fabricated DSSCs exhibited the highest energy conversion efficiency of 5.4% in N719 dye.
引用
收藏
页码:1641 / +
页数:7
相关论文
共 40 条
  • [1] Structure control of organized mesoporous TiO2 films templated by graft copolymers for dye-sensitized solar cells
    Ahn, Sung Hoon
    Koh, Joo Hwan
    Seo, Jin Ah
    Kim, Jong Hak
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (11) : 1935 - 1937
  • [2] Enhancement of photocurrent generation and open circuit voltage in dye-sensitized solar cells using Li+ trapping species in the gel electrolyte
    Benedetti, Joao Eduardo
    de Paoli, Marco Aurelio
    Nogueira, Ana Flavia
    [J]. CHEMICAL COMMUNICATIONS, 2008, (09) : 1121 - 1123
  • [3] In Situ Low Temperature Polymerization of Bismaleimide for Gel-Type Electrolyte for Dye-Sensitized Solar Cells
    Chen, Jian-Ging
    Chen, Chia-Yuan
    Wu, Chun-Guey
    Ho, Kuo-Chuan
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (32) : 13832 - 13837
  • [4] High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells with Organic Dye
    Chen, Peter
    Yum, Jun Ho
    De Angelis, Filippo
    Mosconi, Edoardo
    Fantacci, Simona
    Moon, Soo-Jin
    Baker, Robin Humphry
    Ko, Jaejung
    Nazeeruddin, Md. K.
    Graetzel, Michael
    [J]. NANO LETTERS, 2009, 9 (06) : 2487 - 2492
  • [5] The role of gel electrolyte composition in the kinetics and performance of dye-sensitized solar cells
    de Freitas, Jilian Nei
    Goncalves, Agnaldo de Souza
    de Paoli, Marco-Aurelio
    Durrant, James R.
    Nogueira, Ana Flavia
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (24) : 7166 - 7172
  • [6] Core-shell nanoporous electrode for dye sensitized solar cells:: the effect of the SrTiO3 shell on the electronic properties of the TiO2 core
    Diamant, Y
    Chen, SG
    Melamed, O
    Zaban, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (09) : 1977 - 1981
  • [7] Electron transport analysis for improvement of solid-state dye-sensitized solar cells using poly(3,4-ethylenedioxythiophene) as hole conductors
    Fukuri, Norihiro
    Masaki, Naruhiko
    Kitamura, Takayuki
    Wada, Yuji
    Yanagida, Shozo
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (50) : 25251 - 25258
  • [8] Gebeyehu D., 2002, Synth. Met, V125, P279
  • [9] Characterization of nanocrystalline and thin film TiO2 solar cells with poly(3-undecyl-2,2′-bithiophene) as a sensitizer and hold conductor
    Grant, CD
    Schwartzberg, AM
    Smestad, GP
    Kowalik, J
    Tolbert, LM
    Zhang, JZ
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 522 (01) : 40 - 48
  • [10] A hybrid poly(ethylene oxide)/poly(vinylidene fluoride)/TiO2 nanoparticle solid-state redox electrolyte for dye-sensitized nanocrystalline solar cells
    Han, HW
    Liu, W
    Zhang, J
    Zhao, XZ
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (12) : 1940 - 1944