Characterization of glow-discharge-treated cellulose acetate membrane surfaces for single-layer enzyme electrode studies

被引：28

作者：

Biederman, Hynek ^{[1
]}

Boyaci, Ismail H. ^{[2
]}

Bilkova, Petra ^{[1
]}

Slavinska, Danka ^{[1
]}

Mutlu, Selma ^{[3
]}

Zemek, Josef ^{[4
]}

Trchova, Miroslava ^{[1
]}

Klimovic, Josef ^{[1
]}

Mutlu, Mehmet ^{[2
]}

机构：

[1] Department of Macromolecular Physics, Charles University, V Holesovickach 2, 18000 Praha 8, Czech Republic

[2] Department of Food Engineering, Hacettepe University, Ankara 06532, Turkey

[3] Department of Chemical Engineering, Hacettepe University, Ankara 06532, Turkey

[4] Institute of Physics, Academy of Sciences, Cukrovarnická 10, 16200 Praha 6, Czech Republic

来源：

Journal of Applied Polymer Science | 2001年 / 81卷 / 06期

关键词：

Cellulose - Characterization - Chemical modification - Contact angle - Enzyme immobilization - Enzymes - Fourier transform infrared spectroscopy - Glow discharges - Plasma polymerization - Surface structure - Surface treatment - X ray photoelectron spectroscopy;

D O I：

10.1002/app.1559

中图分类号：

学科分类号：

摘要：

Cellulose acetate membranes (CA) were modified by means of plasma polymerization of ethylene diamine (EDA) and n-butylamine (n-BA). The motivation for this work was the application of a modified membrane for the single-layer enzyme electrode. A tubular reactor with the external radiofrequency (13.56 MHz) excitation was used. Surface modification was performed at 5, 10, and 15 W power (at 27 Pa working pressure) for 5, 10, 15 min. Modified surfaces were characterized in detail by FTIR-ATR, XPS (ESCA), contact angle, and enzyme immobilization activity. The best treatment results were obtained for EDA with 5 W and 30 min and 15 W and 10 min. These results are discussed using surface analysis data.

引用

页码：1341 / 1352