A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate

被引：51

作者：

SINTEF Materials and Chemistry, Postboks 124, Blindern, N-0314, Oslo, Norway ^{[1
]}

不详 ^{[2
]}

机构：

[1] SINTEF Materials and Chemistry, Blindern, N-0314, Oslo

[2] Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, Blindern, N-0315, Oslo

来源：

Dalton Trans. | 2006年 / 17卷 / 2055-2057期

关键词：

24;

D O I：

10.1039/b516365j

中图分类号：

学科分类号：

摘要：

The construction of a scandium coordination polymer from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate, is discussed. Scandium chloride and nitrate react with 2,5-dihydroxyterephthalic acid to form three-dimensional framework compounds in which hexagonally-closed packed inorganic building blocks are linked by the carboxylate groups of organic ligands. The possible to preserve the framework structure and porosity of the scandium polymer could not be determine, however it could still be possible to functionalise the accessible hydroxyl group in reaction carried out in solution. Moreover, one coordination site at the scandium metal is occupied by a solvent molecule which may be easily displaced in a solvent-mediated reaction.

引用

页码：2055 / 2057

页数：2

共 24 条

[1] Perles J., Iglesias M., Ruiz-Valero C., Snejko N., Chem. Commun., pp. 346-347, (2003)
[2] Perles J., Iglesias M., Ruiz-Valero C., Snejko N., J. Mater. Chem., 14, pp. 2683-2689, (2004)
[3] Miller S.R., Wright P.A., Serre C., Loiseau T., Marrot J., Ferey G., Chem. Commun., pp. 3850-3852, (2005)
[4] Perles J., Iglesias M., Martin-Luengo M.-A., Monge M.A., Ruiz-Valero C., Snejko N., Chem. Mater., 17, pp. 5837-5842, (2005)
[5] Dietzel P.D.C., Morita Y., Blom R., Fjellvag H., Angew. Chem., Int. Ed., 44, pp. 6354-6358, (2005)
[6] Dietzel P.D.C., Panella B., Hirscher M., Blom R., Fjellvag H., Chem. Commun., pp. 949-961, (2006)
[7] Barthelet K., Riou R., Ferey G., Chem. Commun., pp. 1492-1493, (2002)
[8] Serre C., Millange F., Surble S., Ferey G., Angew. Chem., Int. Ed., 43, pp. 6285-6290, (2004)
[9] Ferey G., Serre C., Mellot-Draznieks C., Millange F., Surble S., Dutour J., Margiolaki I., Angew. Chem., Int. Ed., 43, pp. 6296-6301, (2004)
[10] Ferey G., Mellot-Draznieks C., Serre C., Millange F., Dutour J., Surble S., Margiolaki I., Science, 309, pp. 2040-2042, (2005)

← 1 2 3 →