Conductometric transducing in electrocatalytical sensors: Detection of ascorbic acid

被引:25
作者
Ivanov, Svetlozar [1 ]
Tsakova, Vessela [1 ]
Mirsky, Vladimir M. [2 ]
机构
[1] Institute of Physical Chemistry, Bulgarian Academy of Sciences
[2] Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, 93040 Regensburg
关键词
Ascorbic acid; Chemical sensor; Conductometric sensor; Electroactive polymers; Electrocatalytical sensor; Poly-ortho-methoxyaniline; Polyaniline;
D O I
10.1016/j.elecom.2006.02.006
中图分类号
学科分类号
摘要
Conductometric transducing is suggested for electrocatalytic chemical sensors based on conductive polymers. Lateral conductivity of the polymer layers was measured by two- and four-point techniques. The approach was applied for electroanalytical detection of ascorbic acid on the electrocatalytically active polyaniline and poly-ortho-methoxyaniline electrodes. Both polymers displayed a monotonous concentration dependence of their conductance in the analytically important sub-millimolar concentration range of ascorbic acid. The approach was tested in model solutions of ascorbic acid in buffer and applied for detection of ascorbic acid in orange juice. © 2006 Elsevier B.V. All rights reserved.
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页码:643 / 646
页数:3
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