Recent findings and prospects in the field of pure metals as negative electrodes for Li-ion batteries

被引：625

作者：

Larcher, Dominique ^{[1
]}

Beattie, Shane ^{[1
]}

Morcrette, Mathieu ^{[1
]}

Edström, Kristina ^{[2
]}

Jumas, Jean-Claude ^{[3
]}

Tarascon, Jean-Marie ^{[1
]}

机构：

[1] Laboratoire de Réactivité et Chimie des Solides, Université de Picardie - Jules Verne, CNRS-UMR 6007, 80039 Amiens Cedex

[2] Department of Materials Chemistry, Ångström Laboratory, Uppsala University

[3] Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques

来源：

Journal of Materials Chemistry | 2007年 / 17卷 / 36期

关键词：

59;

D O I：

10.1039/b705421c

中图分类号：

学科分类号：

摘要：

In the race for better Li-ion batteries, research on anode materials is very intensive as there is a strong desire to find alternatives to carbonaceous negative electrodes. A large part of these studies is devoted to alloying reactions, which have been known for more than thirty years but that have regained great interest by downsizing particle sizes, moving to nano-textured/nanostructured composites, or designing new electrode concepts. It is not the scope of this review to retrace twenty-five years of research, but rather to highlight recent advances that have been made in the use of Sn or Si-based electrodes together with the remaining challenges to be addressed and issues to be solved prior to such electrodes being commercially implemented in Li-ion cells. © The Royal Society of Chemistry 2007.

引用

页码：3759 / 3772

页数：13

共 59 条

[1] Dey A.N., Electrochemial alloying of lithium in organic electrolytes, J. Electrochem. Soc., 118, 10, (1971)
[2] Nicholson M.M., Lithium-magnesium electrodes in propylene carbonate, J. Electrochem. Soc., 121, 6, (1974)
[3] Rao B.M.L., Francis R.W., Christopher H.A., Lithium-aluminum electrode, J. Electrochem. Soc., 124, 10, (1977)
[4] Obrovac M.N., Christensen L., Structural changes in silicon anodes during lithium insertion/extraction, Electrochem. Solid-State Lett., 7, 5, (2004)
[5] Graetz J., Ahn C.C., Yazami R., Fultz B., Highly reversible lithium storage in nanostructured silicon, Electrochem. Solid-State Lett., 6, 9, (2003)
[6] Maranchi J.P., Hepp A.F., Kumta P.N., High capacity reversible silicon thin-film anodes for lithium-ion batteries, Electrochem. Solid-State Lett., 6, 9, (2003)
[7] Maranchi J.P., Hepp A.F., Evans A.G., Nuhfer N.T., Kumta P.N., Interfacial properties of the a-Si/Cu: Active-inactive thin-film anode system for lithium-ion batteries, J. Electrochem. Soc., 153, 6, (2006)
[8] Kulova T.L., Skundin A.M., Pleskov Y.V., Terukov E.I., Kon'Kov O.I., Lithium insertion into amorphous silicon thin-film electrodes, J. Electroanal. Chem., 600, 1, (2007)
[9] Beaulieu L.Y., Hatchard T.D., Bonakdarpour A., Fleischauer M.D., Dahn J.R., Reaction of Li with alloy thin films studied by in Situ AFM, J. Electrochem. Soc., 150, 11, (2003)
[10] Beaulieu L.Y., Eberman K.W., Turner R.L., Krause L.J., Dahn J.R., Colossal reversible volume changes in lithium alloys, Electrochem. Solid-State Lett., 4, 9, (2001)

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