We consider a system of unbiased diffusing walkers (A∅ ↔ ∅A) in one dimension with random initial conditions. We investigate numerically the relation between the fraction of walkers U(t) which have never encountered another walker up to time t, calling such walkers uninfected and the fraction of sites P(t) which have never been visited by a diffusing particle. We extend our study to include the A + B∅ diffusion-limited reaction in one dimension, with equal initial densities of A and B particles distributed homogeneously at t = 0. We find U(t)[P(t)]γ, with γ1.39, in both models, though there is evidence that a smaller value of γ is required for t&rarr∞. © 2002 The American Physical Society.