BOND LENGTHS AND VALENCES IN BaBiO3.

被引：9

作者：

McGuire, N.K. ^{[1
]}

O'Keeffe, M. ^{[1
]}

机构：

[1] Arizona State Univ, Dep of, Chemistry, Tempe, AZ, USA, Arizona State Univ, Dep of Chemistry, Tempe, AZ, USA

来源：

Solid State Communications | 1984年 / 52卷 / 04期

关键词：

D O I：

10.1016/0038-1098(84)90029-2

中图分类号：

O6 [化学]; TQ [化学工业];

学科分类号：

0703 ; 0817 ;

摘要：

Bond length - bond strength correlations are developed for Bi(III) and Bi(V) oxides. Application to the two Bi sites in BaBiO//3 show that these are best described as Bi(III) and Bi(V), respectively, although there is a significant deviation from the ideal valence for the atom identified as Bi(III).

引用

页码：433 / 434