THERMODYNAMICS OF SEVERAL LEWIS-ACID-BASE STABILIZED TRANSITION METAL ALLOYS.

被引:29
作者
Gibson, John K.
Brewer, Leo
Gingerich, Karl A.
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来源
| 1984年 / 15 A期
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D O I
10.1007/BF02646841
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摘要
High-temperature (1425 to 2750 K) thermodynamic activities of one or both components of twenty-five binary alloys of a group IVB-VIB element (Ti, Zr, Hf, Nb, Ta, or W) with a platinum group element (Ru, Os, Ir, Pd, Pt, or Au) have been determined. The stability of this class of alloy is attributed to a generalized Lewis-acid-base interaction involving valence d electrons.
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