STATISTICAL MECHANICS OF ALIPHATIC CHAIN LAYERS, INFLUENCE OF CHAIN-LENGTH MIXING.

被引：6

作者：

Lemaire, B.

Bothorel, P.

机构：

来源：

Journal of polymer science. Part A-2, Polymer physics | 1982年 / 20卷 / 05期

关键词：

Chemical reactions - Emulsions - MATHEMATICAL STATISTICS - Monte Carlo Methods - ORGANIC COMPOUNDS - Chemistry;

D O I：

10.1002/pol.1982.180200509

中图分类号：

学科分类号：

摘要：

In the reported theoretical study, a molecular model is used to simulate interfaces composed of surfactants and cosurfactants in microemulsions where molecules are anchored at the surface or spherical micelles. A Monte Carlo calculation of the conformational properties of the aliphatic layer is carried out taking into account the rotational isomerism of the chains and the binary random distribution of chain lengths. The thermodynamic behavior and the main structural features of the monolayer are analyzed in relation to some micellar properties.

引用

页码：867 / 875