[CN3H6]2[ZN(CO3)2], the first organically templated open-framework carbonate

被引：32

作者：

Harrison, William T.A. ^{[1
]}

Phillips, Mark L.F. ^{[1
]}

Nenoff, Tina M. ^{[1
]}

MacLean, Elizabeth J. ^{[1
]}

Teat, Simon J. ^{[1
]}

Maxwell, Robert S. ^{[1
]}

机构：

[1] Department of Chemistry, University of Aberdeen, Aberdeen, AB24 3UE, United Kingdom

来源：

| 2001年 / Royal Society of Chemistry卷

关键词：

Characterization - Crystal structure - Hydrogen bonds - Hydrothermal synthesis - Nuclear magnetic resonance spectroscopy - Positive ions - Single crystals - X ray diffraction analysis;

D O I：

10.1039/b009641p

中图分类号：

学科分类号：

摘要：

[CN3H6]2[Zn(CO3)2], the first organically templated open-framework carbonate has been synthesized hydrothermally and its single crystal structure and some properties have been determined. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and CO3 building units encapsulating the extra-framework guanidinium cations. Template-to-framework hydrogen bonding appears to play an important role in stabilizing the structure. The zincocarbonate framework shows a surprising similarity to those of known zinc phosphates and phosphites.

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