Results of the field study indicate the seepage can be divided into three hydrochemical zones: (1) the inner core, which is essentially unaltered, acidic seepage from the tailings; (2) the neutralization zone, in which inner-core water is neutralized and aqueous concentrations decrease significantly; and (3) the outer zone, whch contains both neutralized water from the neutralization zone and pH-neutral process water from the uranium milling operation. The main features of the conceptual model are solid-liquid interactions, particularly mineral precipitation-dissolution, and buffering effects of dominant aqueous species. The important minerals undergoing precipitation-dissolution are the calcite-siderite solid solution, gypsum, Al-OH minerals, and Fe-OH minerals. 'Cell and streamtube' calculations are used to evaluate the general trends in aqueous concentrations and to assist in explaining observed migration rates.