Migration of acidic groundwater seepage from uranium-tailings impoundments. I. Field study and conceptual hydrogeochemical model

被引:56
作者
Morin, K.A. [1 ]
Cherry, J.A. [1 ]
Dave, N.K. [1 ]
Lim, T.P. [1 ]
Vivyurka, A.J. [1 ]
机构
[1] Morwijk Enterprises, Vancouver, BC V6G 1Y6, Canada
关键词
GEOCHEMISTRY - Groundwater - HYDROLOGY - URANIUM MINES AND MINING - Waste Disposal - URANIUM ORE TREATMENT - Tailings Disposal;
D O I
10.1016/0169-7722(88)90008-3
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摘要
Results of the field study indicate the seepage can be divided into three hydrochemical zones: (1) the inner core, which is essentially unaltered, acidic seepage from the tailings; (2) the neutralization zone, in which inner-core water is neutralized and aqueous concentrations decrease significantly; and (3) the outer zone, whch contains both neutralized water from the neutralization zone and pH-neutral process water from the uranium milling operation. The main features of the conceptual model are solid-liquid interactions, particularly mineral precipitation-dissolution, and buffering effects of dominant aqueous species. The important minerals undergoing precipitation-dissolution are the calcite-siderite solid solution, gypsum, Al-OH minerals, and Fe-OH minerals. 'Cell and streamtube' calculations are used to evaluate the general trends in aqueous concentrations and to assist in explaining observed migration rates.
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页码:271 / 303
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