Superconducting properties of a new series Bi2-xSbxSr2Ca2Cu3Oy (x=0.05, 0.1, 0.15, 0.2) have been reported in this paper. All of these samples have two superconducting transitions. The first superconducting transition is at about 120 K, zero resistance temperature is about 75 K. A new high-Tc phase appears because of the substitution of Sb in the Bi-Sr-Ca-Cu-O system.