DSC STUDIES OF AROMATIC HYDROCARBON PICRATES

被引：20

作者：

FARRELL, PG ^{[1
]}

SHAHIDI, F ^{[1
]}

CASELLATO, F ^{[1
]}

VECCHI, C ^{[1
]}

GIRELLI, A ^{[1
]}

机构：

[1] STAZIONE SPERIMENTALE PER COMBUST,I-20097 MILAN,ITALY

来源：

THERMOCHIMICA ACTA | 1979年 / 33卷 / OCT期

关键词：

D O I：

10.1016/0040-6031(79)87051-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Melting temperatures, enthalpies and entropies of fusion of a number of crystalline, charge-transfer complexes of aromatic hydrocarbons with 2,4,6-trinitrophenol (picric acid) have been measured, together with the corresponding data for some aromatic hydrocarbons themselves and for picric acid. The data suggest that for this, and for other nitro-aromatic acceptor molecules, enthalpies of fusion of charge-transfer complexes reflect the complexing ability of the electron acceptor, although the contribution of the charge-transfer interaction to the measured enthalpy is small. © 1979.

引用

页码：275 / 280

页数：6

共 15 条

[1] BRIEGLEB G, 1955, Z ELEKTROCHEM, V59, P184
[2] Briegleb G., 1959, Z. physik. Chem, V21, P99
[3] Butylnaphthalenes and their derivatives - Part I beta-tert-butylnaphthalene
Bromby, NG
Peters, AT
Rowe, TM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1943, : 144 - 146
[4] DSC STUDY OF CHARGE-TRANSFER COMPLEXES OF POLYNUCLEAR AROMATIC-HYDROCARBONS WITH NITROAROMATIC ACCEPTORS
CASELLATO, F
VECCHI, C
GIRELLI, A
FARRELL, PG
[J]. THERMOCHIMICA ACTA, 1975, 13 (01) : 37 - 45
[5] CASELLATO F, 1977, CHEM IND-LONDON, P83
[6] DIFFERENTIAL SCANNING CALORIMETRY STUDY OF CHARGE-TRANSFER COMPLEXES OF POLYNUCLEAR AROMATIC-HYDROCARBONS WITH ASYMMETRIC ACCEPTORS 3-NITROPHTHALIC AND 4-NITROPHTHALIC ANHYDRIDE
CASELLATO, F
VECCHI, C
GIRELLI, A
[J]. THERMOCHIMICA ACTA, 1977, 21 (02) : 195 - 199
[7] CASELLATO F, CHIM IND MILAN
[8] Casellato F., 1973, Thermochimica Acta, V6, P361, DOI [DOI 10.1016/0040-6031(73)87003-0, 10.1016/0040-6031(73)87003-0]
[9] CASELLATO F, 1978, GAZZ CHIM ITAL, V108, P21
[10] FARRELL PM, UNPUBLISHED

← 1 2 →