共 2 条
四(对-羟基)苯基卟啉配合物的傅里叶变换红外光声光谱
被引:20
作者:
师同顺
安庆大
徐春放
刘国发
滕永富
齐向丽
于连香
机构:
[1] 吉林大学化学系!长春,
[2] 大连轻工业学院
[3] 大庆高等专科学校
来源:
关键词:
红外光声光谱;
过渡金属;
卟啉配合物;
D O I:
暂无
中图分类号:
O657.33 [红外光谱分析法];
学科分类号:
070302 ;
081704 ;
摘要:
The Fourier Transform infrared photoacoustic spectra of tetra-(para-hydro-xyphenyl) porphyrin and its Cr(III), Mn(III), Fe(III), Co(II), Ni (II), Cu (II) and Zn(II) complexes in the range 3700~200cm-1 were measured and investigated. There exist intermolecular hydrogen bonds in the porphyrin and its complexes. The vibration coupling between the M-N stretching and the porphyrin ring deformation appears at 250cm-1. The band at 316cm-1 is stretching vibration of M(III)-Cl. Metal sensitive bands were found at about 1550, 1350, 1076, 1000 and 250cm-1.
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页数:3
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