NO-NH3-O2reactioncatalyzedbyV2O5/ACatlowtemperatures——EffectsofSO2,V2O5loadingandreactiontemperature

被引:5
作者
朱珍平
刘振宇
牛宏贤
刘守军
机构
[1] State Key Laboratory of Coal Conversion
[2] Institute of Coal Chemistry
[3] Chinese Academy of Sciences
[4] Taiyuan
[5] China
关键词
V2O5/AC catalyst; NO reduction; ammonia; sulfur dioxide;
D O I
暂无
中图分类号
O643.3 [催化];
学科分类号
081705 ;
摘要
<正> The effects of SO2, V2O5 loading and reaction temperature on the activity of activated carbon supported vanadium oxide catalyst have been studied for the reduction of NO with NH3 at low temperatures (150-250℃). It is found that SO2 significantly promotes the catalyst activity. Both V2O5 loading and reaction temperature are vital to the promoting effect of SO2. The catalysts with V2O5 loadings of 1 -5 weight percent have a positive effect on the promotion of SO2, while the catalysts with V2O5 loadings of above 7 weight percent have not such an effect or show a negative effect. At lower temperatures (<180℃) SO2 poisons the catalyst but at higher temperatures promotes it. The reason of the SO2 promotion was also discussed; it may results from the formation of SO42- on the catalyst surface, which increases the surface acidity and hence the catalytic activity.
引用
收藏
页码:51 / 57
页数:7
相关论文
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[1]  
Reactivity of V 2 O 5 Catalysts for the Selective Catalytic Reduction of NO by NH 3 : Influence of Vanadia Loading, H 2 O, and SO 2[J] . Michael D Amiridis,Israel E Wachs,Goutam Deo,Jih-Mirn Jehng,Du Soung Kim.Journal of Catalysis . 1996 (1)