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INFLUENCE OF TEMPERATURE AND PRESSURE ON THE KINETICS OF Mg-6mol%LaNi PREPARED BY HYDRIDING COMBUSTION SYNTHESIS
被引：1
作者：
Q Li KC Chou KD Xu LJ Jiang JY Zhang and XG Lu School of Materials Science and Engineering Shanghai University Shanghai China Department of Physical Chemistry University of Science and Technology Beijing Beijing China General Research Institute for Nonferrous Metals Beijing China
[200072
,100083
,100088
]
机构：
关键词：
powder metallurgy;
hydrogen storage materials;
kinetics;
D O I：
暂无
中图分类号：
O611.3 [性质];
学科分类号：
070301 ;
081704 ;
摘要：
<正>A new model to study the hydriding/dehydriding (H/D) kinetic mechanism has been applied in the two-phase (α-β) region of the Mg-6mol%LaNi composite at temperature and pressure ranging from 523 to 623K and 0.256 to 0.992MPa H2, respectively. The coincidence of the theoretical calculation with the experimental data indicates that the rate-limiting step is hydrogen diffusion in the (3 phase for hydriding process and the diffusion of hydrogen in the a solid solution for hydrogen desorption with activation energies 89500 and 87900J/mol H2for H/D processes, respectively, which were much smaller than those of MgH2 and can be attributed to the La and Ni additions.
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页码：124 / 132
页数：9
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