未找到相关数据
稀土乙酰丙氨酸咪唑配合物的合成及光谱性质
被引：35
作者：
杨一心
王艳
赵天成
王党辉
郝惠娣
武祥龙
谢志海
机构：
[1] 西北大学化学系,西北大学化学系,西北大学化工学院,西北大学化学系,西北大学化工学院,西北大学化学系,西北大学化学系 西安,西安
[2] 湖北民族学院化学与环境工程学院,恩施,西安,西安,西安,西安,西安
来源：
关键词：
稀土配合物;
N-乙酰-DL-丙氨酸;
咪唑;
光谱性质;
D O I：
暂无
中图分类号：
O627.33 [钪族元素有机化合物];
学科分类号：
070303 [有机化学];
摘要：
Two new coordination compounds of rare earth chloride with N-acetyl-DL-alanine and imidazole have been prepared from absolute alcohol. The general formula RE(C5H8NO3)2(C3H5N2)2Cl3·4H2O (RE=Ce, Pr) of these compounds were identified, by chemical and elemental analysis, FTIR spectra, UV spectra, 1H NMR and 13C NMR spectra, and molar conductance. The processes of thermal decomposition were identified by TG-DSC curves. The possible reaction mechanisms and the kinetics equation were investigated by comparing the kinetics parameters. The activation entropy of dehydration, as well as enthalpy values of dehydration and decomposition were obtained by DSC curve. The three-dimensional fluorescence spectra of liquid compounds were measured. The phenomenon of the up-conversion fluorescence is discussed.
引用
收藏
页码：578 / 582+449
+449
页数：6
相关论文