亚氨基二乙酸树脂吸附钇(Ⅲ)的研究(英文)

被引:16
作者
熊春华
吴香梅
机构
[1] 杭州商学院食品、生物技术和环境工程学院
[2] 丽水师范专科学校化学系 杭州
[3] 丽水
基金
浙江省自然科学基金;
关键词
亚氨基二乙酸树脂; 钇; 吸附; 机理;
D O I
暂无
中图分类号
O647.3 [吸附];
学科分类号
070304 ; 081704 ;
摘要
The adsorption behavior and mechanism of a novel chelate resin, iminodiacetic acid resin (IDAAR) for Y? were investigated. The statically saturated adsorption capacity is 102mg· g- 1 resin at 298K in HAc NaAc medium at pH 5.7. Y? adsorbed on IDAAR can be reductively eluted by 1.0~ 4.0mol· L- 1 HCl used as eluant and the elution percentages are almost as high as 100% . The resin can be regenerated and reused without apparent decrease in adsorption capacity. The apparent adsorption rate constant is k298=3.36× 10- 5s- 1. The adsorption behavior of IDAAR for Y? conforms to Freundlich′ s model reasonably. The thermodynamic adsorption parameter, enthalpy change Δ H of IDAAR for Y? is 18.6kJ· mol- 1. The complex molar ratio of the functional group of IDAAR to Y? is about 3∶ 1. The adsorption mechanism of IDAAR for Y? was examined by using chemical method and IR spectrometry.
引用
收藏
页码:1356 / 1360
页数:5
相关论文
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金属分析中的有机试剂.[M].[苏]拉扎列夫(А·И·Лазарев) 著;孙淑媛;孙龄高 译.北京师范大学出版社.1983,
[2]  
吸附的基础与设计.[M].[日]北川浩;[日]铃木谦一郎 著;鹿政理 译.化学工业出版社.1983,