低共熔溶剂在混合物分离中的应用

被引:60
作者
侯玉翠 [1 ]
王震 [2 ]
任树行 [2 ]
吴卫泽 [2 ]
机构
[1] 太原师范学院化学系
[2] 北京化工大学化学工程学院,化工资源有效利用国家重点实验室
基金
高等学校博士学科点专项科研基金;
关键词
低共熔溶剂; 物化性质; 混合物分离; 过程特点; 进展;
D O I
暂无
中图分类号
TQ413 [溶剂];
学科分类号
082903 [林产化学加工工程];
摘要
低共熔溶剂(DES)是一种新型的绿色溶剂,由于其独特的特性,如合成容易、成本低、环境友好、挥发性小、溶解能力强、可设计性等,在混合物分离方面得到广泛的应用.本文介绍了DES的物理化学性质,论述了DES在酸性气体(CO2,SO2和H2S)的分离、生物柴油中副产物的分离、燃料油脱硫、油中酚类化合物分离、油中芳烃的分离、苯羧酸同分异构体的分离、金属氧化物或者盐的分离、萃取天然产物、醇和酯混合物分离等方面的研究进展,分析了这些基于DES的分离过程的特点,探讨了DES在这些混合物分离过程中存在的问题,并提出了未来的发展建议.
引用
收藏
页码:2490 / 2499
页数:10
相关论文
共 11 条
[1]
胆碱类低共融溶剂在CO2捕集与分离中的应用 [J].
张盈盈 ;
吉晓燕 ;
陆小华 .
化工学报, 2014, 65 (05) :1721-1728
[2]
Separation of toluene from toluene/alkane mixtures with phosphonium salt based deep eutectic solvents.[J].Yucui Hou;Zhongyi Li;Shuhang Ren;Weize Wu.Fuel Processing Technology.2015,
[3]
Carbon dioxide solubility in a deep eutectic solvent based on choline chloride and urea at T <ce:hsp sp="0.25"/>=<ce:hsp sp="0.25"/>303.15–343.15<ce:hsp sp="0.25"/>K and moderate pressures.[J].Rhoda B. Leron;Alvin Caparanga;Meng-Hui Li.Journal of the Taiwan Institute of Chemical Engineers.2013, 6
[4]
Phase equilibria of toluene/heptane with deep eutectic solvents based on ethyltriphenylphosphonium iodide for the potential use in the separation of aromatics from naphtha.[J].Mukhtar A. Kareem;Farouq S. Mjalli;Mohd Ali Hashim;Mohamed K.O. Hadj-Kali;Fatemeh Saadat Ghareh Bagh;Inas M. Alnashef.The Journal of Chemical Thermodynamics.2013,
[5]
Simultaneous production of small-molecule fatty acids and benzene polycarboxylic acids from lignite by alkali-oxygen oxidation.[J].Wenhua Wang;Yucui Hou;Weize Wu;Muge Niu.Fuel Processing Technology.2013,
[6]
Practical separation of alcohol–ester mixtures using Deep-Eutectic-Solvents.[J].Zaira Maugeri;Walter Leitner;Pablo Domínguez de María.Tetrahedron Letters.2012, 51
[7]
Prediction of the surface tension of deep eutectic solvents.[J].K. Shahbaz;F.S. Mjalli;M.A. Hashim;I.M. AlNashef.Fluid Phase Equilibria.2012,
[8]
A new low transition temperature mixture (LTTM) formed by choline chloride<ce:hsp sp="0.25"/>+<ce:hsp sp="0.25"/>lactic acid: Characterization as solvent for CO 2 capture.[J].María Francisco;Adriaan van den Bruinhorst;Lawien F. Zubeir;Cor J. Peters;Maaike C. Kroon.Fluid Phase Equilibria.2012,
[9]
Liquid–liquid equilibria for the ternary system (phosphonium based deep eutectic solvent–benzene–hexane) at different temperatures: A new solvent introduced.[J].Mukhtar A. Kareem;Farouq S. Mjalli;Mohd Ali Hashim;Inas M. AlNashef.Fluid Phase Equilibria.2011,
[10]
A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids.[J].Maan Hayyan;Farouq S. Mjalli;Mohd Ali Hashim;Inas M. AlNashef.Fuel Processing Technology.2009, 1