Fractionation of Heavy Metals in Soils as Affected by Soil Types and Metal Load Quantity

被引:21
作者
ZHOU DONGMEI
机构
关键词
fraction; heavy metal; interaction; ionic impulsion; soil;
D O I
暂无
中图分类号
S153 [土壤化学、土壤物理化学];
学科分类号
0903 ; 090301 ;
摘要
Two series of soil subsamples, by spiking copper (Cu), lead (Pb), zinc (Zn) and cadmium (Cd) in an orthogonal design, were prepared using red soil and brown soil, respectively. The results indicated that heavy metal fractions in these soil subsamples depended not only on soil types, but also on metal loading quantity as well as on interactions among metals in soil. Lead and Cu in red soil appeared mostly in weakly specifically adsorbed (WSA), Fe and Mn oxides bound (OX), and residual (RES) fractions. Zinc existed in all fractions except organic bound one, and Cd was major in water soluble plus exchangeable (SE) one. Different from the results of red soil, Pb and Cu was present in brown soil in all fractions except organic one, but over 75% of Zn and 90% of Cd existed only in SE fraction. Meanwhile, SE fraction for any metal in red soil was lower than that in brown soil and WSA and OX fractions were higher. It is in agreement with low cation exchange capacity and large amounts of metal oxides included in
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页码:309 / 319
页数:11
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