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全芳型超支化聚酯的合成及端基改性
被引：4
作者：
唐黎明
机构：
[1] 清华大学化工系和材料科学与工程研究院!北京
来源：
关键词：
芳香聚合物;
超支化聚酯;
合成;
端基改性;
D O I：
暂无
中图分类号：
O631 [高分子物理和高分子物理化学];
学科分类号：
070305 ;
080501 ;
081704 ;
摘要：
Soluble aromatic hyperbranched polyesters with controlled viscosities have been prepared by melt polycondensation of sililated 5 acetoxyisophathalic acid with sililated p tert butyl benzoic acid in various molar ratios. By further reaction with thionyl chloride and propargyl alcohol successively, the endgroups of the crude polyester were transferred into ethynylic groups in 78 2% yield as calculated by 1H NMR spectra.
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页码：340 / 341
页数：2
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