QuEChERS法-液相色谱-串联质谱法测定蔬菜中7种农药及其代谢物的残留量

被引：28

作者：

王建华 ^{[1
]}

葛敏敏 ^{[2
]}

张慧丽 ^{[2
]}

林洪 ^{[2
]}

汤志旭 ^{[1
]}

李立 ^{[3
]}

机构：

[1] 山东出入境检验检疫局检验检疫技术中心

[2] 中国海洋大学食品科学与工程学院

[3] 中国检验检疫科学研究院

来源：

食品科学 | 2017年 / 38卷 / 20期

关键词：

液相色谱-串联质谱; 蔬菜; 农药及其代谢物;

D O I：

暂无

中图分类号：

O657.63 [质谱分析]; TS255.7 [果蔬加工品标准与检验];

学科分类号：

070302 [分析化学]; 083203 [农产品加工及贮藏工程];

摘要：

样品经乙腈提取,C18吸附剂和石墨化碳黑分散固相萃取净化,液相色谱-三重四极杆串联质谱在动态多反应监测模式下检测,基质匹配标准曲线外标法进行定量,建立了蔬菜中7种农药及其代谢物的多残留分析方法。在10、20μg/kg 7种农药及其添加物添加水平下,农药及其代谢物的平均回收率为71.9%117.8%,相对标准偏差为0.8%9.6%,定量限为0.2～10μg/kg。该方法简便、快速、灵敏,适用于蔬菜中多种农药及其代谢物的同时检测。

引用

页码：235 / 241

页数：7

共 11 条

[1]

Validation of QuEChERS method for the determination of 36 pesticide residues in fruits and vegetables from Ghana, using gas chromatography with electron capture and pulsed flame photometric detectors [J].

Donkor, Augustine ;

Osei-Fosu, Paul ;

Nyarko, Stephen ;

Kingsford-Adaboh, Robert ;

Dubey, Brajesh ;

Asante, Isaac .

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 2015, 50 (08) :560-570

[2]

A simple multi-residue method for the determination of pesticides in fruits and vegetables using a methanolic extraction and ultra-high-performance liquid chromatography-tandem mass spectrometry: Optimization and extension of scope.[J].V. Hanot;S. Goscinny;M. Deridder.Journal of Chromatography A.2015,

[3]

Residue analysis of fipronil and difenoconazole in okra by liquid chromatography tandem mass spectrometry and their food safety evaluation.[J].Sandip Hingmire;Dasharath P. Oulkar;Sagar C. Utture;T.P. Ahammed Shabeer;Kaushik Banerjee.Food Chemistry.2015,

[4]

Evaluation of QuEChERS sample preparation and liquid chromatography–triple-quadrupole mass spectrometry method for the determination of 109 pesticide residues in tomatoes.[J].Ozgur Golge;Bulent Kabak.Food Chemistry.2015,

[5]

Development and method validation for determination of 128 pesticides in bananas by modified QuEChERS and UHPLC–MS/MS analysis.[J].Raphaella P. Carneiro;Fabiano A.S. Oliveira;Fernando D. Madureira;Gilsara Silva;Wesley R. de Souza;Renata Pereira Lopes.Food Control.2013, 2

[6]

Multiresidue determination of 375 organic contaminants including pesticides; polychlorinated biphenyls and polyaromatic hydrocarbons in fruits and vegetables by gas chromatography–triple quadrupole mass spectrometry with introduction of semi-quantification approach.[J].Kaushik Banerjee;Sagar Utture;Soma Dasgupta;Chandrasekar Kandaswamy;Saswati Pradhan;Sunil Kulkarni;Pandurang Adsule.Journal of Chromatography A.2012,

[7]

Fast, low-pressure gas chromatography triple quadrupole tandem mass spectrometry for analysis of 150 pesticide residues in fruits and vegetables [J].

Koesukwiwat, Urairat ;

Lehotay, Steven J. ;

Leepipatpiboon, Natchanun .

JOURNAL OF CHROMATOGRAPHY A, 2011, 1218 (39) :7039-7050

[8]

Validation and use of a fast sample preparation method and liquid chromatography–tandem mass spectrometry in analysis of ultra-trace levels of 98 organophosphorus pesticide and carbamate residues in a total diet study involving diversified food types.[J].Stephen W.C. Chung;Benny T.P. Chan.Journal of Chromatography A.2010, 29

[9]

Volume-load capacity in fast-gradient liquid chromatography.[J].J. Layne;T. Farcas;I. Rustamov;F. Ahmed.Journal of Chromatography A.2001, 1

[10]

浅谈样品溶剂对高效液相色谱行为的影响 [J].

王丽 ;

申兰慧 ;

陈国清 .

中国药事, 2013, 27 (02) :163-166

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