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喹啉衍生物自组装单分子膜的制备与结构
被引：3
作者：
张浩力
张华
张锦
吴斌
刘忠范
力虎林
机构：
[1] 兰州大学化学系!兰州,,北京大学化学与分子工程学院!北京,,兰州大学化学系!兰州,,北京大学化学与分子工程学院!北京,,北京大学化学与分子工程学院!北京,,兰州大学化学系!兰州,
来源：
关键词：
喹啉衍生物;
自组装单分子膜;
反射红外光谱;
分子取向;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
摘要：
A novel quinoline derivative 6-(10-thiol-decaoxy ) quinoine (abbreviated as QC10SH )was synthesized and its seif-assembled monoayers (SAMs) were prepared on gold for the first time. Wettability measurement on QC10SH SAM reveals a hydrophilic surface. RA-IR researches suggests that the SAM has formed highly-organized and closely-packed structure. A method is developed for quanitatively evaluating the molecular orientation in monoayer. By this method the result that the twisting and tilting angles of QC10SH moecule in SAM are 50±4° and 24±3°respectively has been obtained.
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页码：657 / 661
页数：5
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