磷灰石结构中[SO4]、[SiO4]四面体的喇曼谱学特点

被引：3

作者：

刘羽

机构：

[1] 武汉化工学院!武汉

来源：

矿物岩石地球化学通报 | 1999年 / 04期

关键词：

磷灰石; SiO4四面体; SO4四面体; 喇曼光谱;

D O I：

暂无

中图分类号：

P578.922 [];

学科分类号：

摘要：

The Raman spectra of synthetic hydroxyapatite (HAP), natural silicate, sulfate bearing apatite (NAP) and ellestadite (ELLE) were compared. Raman characteristics of [SO 4],[SiO 4] tetrahedra in apatite structure were discussed. As [SiO 4] and [SO 4] enter the structure, their Raman intensity increases and that of [PO 4] decreases. The ν 1 peaks of [PO 4],[SiO 4],[SO 4] shift to lower wave number region as tetrahedra T P bong length and volume of unit cell increase.

引用

页码：241 / 243

页数：3