三唑酮氯化锌配合物的合成和晶体结构研究

被引：7

作者：

张培志

吴军

龚钰秋

胡秀荣

顾建明

机构：

[1] 浙江科技学院生物与化学工程学系

[2] 浙江大学化学系

[3] 浙江大学分析测试中心

来源：

无机化学学报 | 2003年 / 07期

基金：

浙江省自然科学基金;

关键词：

三唑酮; 锌配合物; 合成; 晶体结构;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

摘要：

ZThe new compound was synthesized by the reaction of ZnCl2 and triadimefon(ratio 1∶ 2) in ethanol solution refluxing for 6 hours. The crystal used for X ray analysis was obtained by slow evaporation of the solution at room temperature. It crystallizes in the monoclinic system, space group P2/n. The lattice parameters are: a=1.58916(6)nm, b=0.60634(2)nm, c=1.83566(8)nm, β =93.979(2)° , V=1.7645(1)nm3, Z=2, Dc=1.362g· cm- 3, F(000)=744.00, μ (MoKα )=1.038mm- 1, R1=0.042, wR2=0.106. In the complex, the Zn(Ⅱ) cation is tetrahedrally coordinated to two triadimefon ligands and two chloride in cis disposition. The title complex was also characterized by elemental analysis, molar conductance, IR and TG DTA. CCDC: 207413.

引用

页码：753 / 756

页数：4