紫外光聚合法制备L-DBTA手性分子印迹聚合物的研究 Ⅰ.紫外光聚合制备条件

被引：2

作者：

杨座国

许振良

机构：

[1] 华东理工大学化学工程研究所

来源：

功能高分子学报 | 2005年 / 01期

关键词：

分子印迹; L-DBTA; 光聚合; 手性识别;

D O I：

10.14133/j.cnki.1008-9357.2005.01.008

中图分类号：

TQ316.3 [聚合反应过程];

学科分类号：

摘要：

以丙烯酸为功能单体,二苯甲酰 L 酒石酸(L DBTA)为模板分子,三羟甲基丙烷三丙烯酸酯(TMPTA)为交联剂,采用光聚合方法合成了 L DBTA手性分子印迹聚合物,讨论了功能单体种类、功能单体用量、交联剂用量、引发剂用量、三乙胺用量、光聚合温度、光聚合时间、光强度等对L DBTA手性分子印迹聚合物合成的影响。通过L DBTA手性分子印迹聚合物对底物的结合实验分析,表明手性分子印迹聚合物对L DBTA具有很好的识别性, L DBTA的选择性比二苯甲酰 D 酒石酸(D DBTA)高,其分离因子可达5.41。

引用

页码：36 / 41

页数：6

共 8 条

[1] Molecularly imprinted uniform-sized polymer-based stationary phase for naproxen. J Haginaka,H Takekira,K Hosoya,et al. Journal of Chromatography A . 1 9 9 8
[2] Molecularly imprinted polymeric membranes with oligopeptide tweezers for optical resolution. Yoshikawa,Masakazu Yonetani,Kyoichi. Desalination . 2 0 0 2
[3] Molecular imprinted polymers for solid-phase extraction. Stevenson Derek. Trends in Analytical Chemistry Volume . 1 9 9 9
[4] Imprinted chiral stationary phases in high-performance liquid chromatography. Borje Sellergren. Journal of Chromatography A . 2 0 0 1
[5] Noncovalent molecular imprinting: antibody-like molecular recognition in polymeric network materials. Sellergren,B rje. Trends in Analytical Chemistry . 1 9 9 7
[6] Making an impression: synthesis and use of molecular imprints of a development compound. Venn Richard F,Goody Robin. European Journal of Pharmaceutical Sciences . 1 9 9 6
[7] Molecularly imprinted polymers for biosensor applications. Yano Kazuyoshi,Karube Isao. Trends in Analytical Chemistry . 1 9 9 9
[8] Molecularly imprinted polymer membranes for substance-selective solid-phase extraction from water by surface photo-grafting polymerization. Tatiana A S,Heike Matuschewski,Sergiy A P,etc. Journal of Chromatography A . 2 0 0 1

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