共 3 条
[3]
Organic Syntheses Coll .2 Horning E. C. John Wiles &Sons . 1955
乙腈介质中S—NO键异裂能和均裂能的测定
被引：3
作者：
吕健明
朱晓晴
李倩
何家骐
鲜明
程津培
机构：
[1] 南开大学化学系!天津
来源：
关键词：
NO亲合势;
S-亚硝基化合物;
S—NO键能;
滴定量热法;
D O I：
暂无
中图分类号：
O641 [结构化学];
学科分类号：
070304 ;
081704 ;
摘要：
Heterolytic and homolytic SNO bond dissociation energies are determined in acetonitrile at 25 ℃ by using titration calorimetry and electrochemical measurements with a well designed thermodynamic cycle. The results suggest that SNO compounds in vivo may release NO in a manner of homolytic bond dissociation. Other effects that influence the bond energies are also discussed. [WT5HZ]
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页码：570 / 572
页数：3
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