改性活性炭脱除二氧化碳中的微量苯

被引:7
作者
李玉雪
张永春
机构
[1] 大连理工大学精细化工国家重点实验室
关键词
活性炭; 苯; 吸附; 湿氧化改性;
D O I
暂无
中图分类号
TQ116.3 [二氧化碳的生产];
学科分类号
0817 ;
摘要
It is significant to recover CO2 from industrial tail gases.Adsorption of low concentration benzene on activated carbon was studied.Activated carbon was treated with wet oxidized reagent and N2 reduction.Pore structure of modified activated carbon was characterized by N2(77 K) adsorption isotherm.Boehm titration,Fourier transform infrared spectroscopy(FTIR) were used to characterize the surface properties.N2 reduction increased the surface area of AC and total pore volume,reduced the amount of surface groups and improved benzene adsorption.With CO2 regeneration at 150℃,the capability of activated carbon adsorbents had a little decrease at the beginning but remained unchanged with recycling.
引用
收藏
页码:1494 / 1499
页数:6
相关论文
共 13 条
[1]   活性炭孔结构和表面化学性质对吸附硝基苯的影响 [J].
刘守新 ;
陈曦 ;
张显权 .
环境科学, 2008, (05) :1192-1196
[2]   苯及苯类化合物对人体的影响 [J].
刘晶秋 ;
张小洁 ;
程功 ;
方桂艳 .
中国实用医药, 2007, (04) :97-97
[3]   烟道气回收CO2的工业应用 [J].
叶宁 ;
毕亚军 .
化学工程师, 2005, (10) :62-64
[4]   表面化学改性吸附用活性炭的研究进展 [J].
王鹏 ;
张海禄 .
炭素技术, 2003, (03) :23-28
[5]   改性活性炭对苯废气吸附性能的研究 [J].
张丽丹 ;
赵晓鹏 ;
马群 ;
王琪 ;
郭坤敏 .
新型炭材料, 2002, (02) :41-44
[6]   湿氧化改性多孔炭对低浓度苯和丁酮蒸汽的吸附 [J].
黄正宏 ;
康飞宇 ;
吴慧 ;
梁开明 .
清华大学学报(自然科学版), 2000, (10) :111-115
[7]   几种活性炭表面酸性基团的测定及其对吸附性能的影响 [J].
邱介山,王艳斌,邓贻钊 .
炭素技术, 1996, (04) :11-17
[8]   Surface chemistry of phosphorus-containing carbons of lignocellulosic origin [J].
Puziy, AM ;
Poddubnaya, OI ;
Martínez-Alonso, A ;
Suárez-García, F ;
Tascón, JMD .
CARBON, 2005, 43 (14) :2857-2868
[9]   Role of surface chemistry in adsorption of phenol on activated carbons [J].
Salame, II ;
Bandosz, TJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 264 (02) :307-312
[10]  
Surface Chemistry of Activated Carbons: Combining the Results of Temperature-Programmed Desorption, Boehm, and Potentiometric Titrations[J] . Issa I. Salame,Teresa J. Bandosz.Journal of Colloid And Interface Science . 2001 (1)