生物质超临界水气化制氢技术的研究现状

被引：5

作者：

徐东海

王树众

张钦明

李

王亮

机构：

[1] 西安交通大学动力工程多相流国家重点实验室

来源：

现代化工 | 2007年 / S1期

关键词：

超临界水; 生物质; 气化; 制氢;

D O I：

10.16606/j.cnki.issn0253-4320.2007.s1.009

中图分类号：

TQ116.2 [氢气];

学科分类号：

0817 ;

摘要：

介绍了国内外生物质超临界水气化制氢技术的研究进展,并对该技术的反应机理、影响因素、不同的催化剂、催化机理进行了评述。指出对气化反应机理的研究应该以关键化合物为基础;在反应器形式和催化剂一定的条件下,影响气化结果的主要因素是反应温度、进料浓度、加热速率、碱性化合物添加剂;碱性化合物添加剂和碳催化剂或金属催化剂结合使用可能会实现高效催化气化过程。

引用

页码：88 / 92

页数：5

共 13 条

[1] 化学制氢技术研究进展 [J].

吴川 ;

张华民 ;

衣宝廉 .

化学进展, 2005, (03) :423-429

[2]

Hydrogen production from catalytic gasification of cellulose in supercritical water[J] . Xiaohong Hao,Liejin Guo,Ximin Zhang,Yu Guan.Chemical Engineering Journal . 2005 (1)

[3]

Biomass gasification in near- and super-critical water: Status and prospects[J] . Yukihiko Matsumura,Tomoaki Minowa,Biljana Potic,Sascha R.A. Kersten,Wolter Prins,Willibrordus P.M. van Swaaij,Bert van de Beld,Douglas C. Elliott,Gary G. Neuenschwander,Andrea Kruse,Michael Jerry Antal Jr..Biomass and Bioenergy . 2005 (4)

[4] Glucose reactions within the heating period and the effect of heating rate on the reactions in hot compressed water [J].

Watanabe, M ;

Aizawa, Y ;

Iida, T ;

Levy, C ;

Aida, TM ;

Inomata, H .

CARBOHYDRATE RESEARCH, 2005, 340 (12) :1931-1939

[5] Catalytic hydrogen generation from biomass (glucose and cellulose) with ZrO2 in supercritical water [J].

Watanabe, M ;

Inomata, H ;

Arai, K .

BIOMASS & BIOENERGY, 2002, 22 (05) :405-410

[6]

Developing an innovative method, HyPr-RING, to produce hydrogen from hydrocarbons[J] . Shi-Ying Lin,Yoshizo Suzuki,Hiroyuki Hatano,Michiaki Harada.Energy Conversion and Management . 2002 (9)

[7] Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water [J].

Bühler, W ;

Dinjus, E ;

Ederer, HJ ;

Kruse, A ;

Mas, C .

JOURNAL OF SUPERCRITICAL FLUIDS, 2002, 22 (01) :37-53

[8] Development of a solution model to correlate solubilities of inorganic compounds in water vapor under high temperatures and pressures [J].

Shin, HY ;

Matsumoto, K ;

Higashi, H ;

Iwai, Y ;

Arai, Y .

JOURNAL OF SUPERCRITICAL FLUIDS, 2001, 21 (02) :105-110

[9] Hydrothermal gasification of biomass and organic wastes [J].

Schmieder, H ;

Abeln, J ;

Boukis, N ;

Dinjus, E ;

Kruse, A ;

Kluth, M ;

Petrich, G ;

Sadri, E ;

Schacht, M .

JOURNAL OF SUPERCRITICAL FLUIDS, 2000, 17 (02) :145-153

[10]

Cellulose decomposition in hot-compressed water with alkali or nickel catalyst[J] . Tomoaki Minowa,Fang Zhen,Tomoko Ogi.The Journal of Supercritical Fluids . 1998 (1)

← 1 2 →