具二维网格的氟喹诺酮类铜配合物的合成和晶体结构

被引：7

作者：

王国平

蔡国强

朱龙观

机构：

[1] 浙江大学化学系! 杭州

来源：

无机化学学报 | 2000年 / 06期

关键词：

合成; 晶体结构; 铜; 氟喹诺酮类;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The 2 D coordination polymer network containing fluoroquinolone ligand, {[Cu(L)(bipy)](C2H5OH)(5H2O)}n, was synthesized and its crystal structure was solved. The formula of the complex is C30H40N5FO11Cu and the crystallography data are as follows, monoclinic, space group P21/c(No.14),a=11.937(3)? ,b=10.555(3)? ,c=25.293(9)? ,β =98.82(3)°， V= 3148(1)? 3 and Z=4。 Two carboxylate groups monodentately bind to copper atoms and the 4 oxo group is linked to copper atom. The Cu ion displays a distorted square pyramidal coordination and its coordination number is five.

引用

页码：987 / 990

页数：4

共 4 条

[1] 配位聚合物 [J].