共 3 条
[1]
电解质溶液理论导论.[M].黄子卿 著.科学出版社.1983,
[2]
[3]
用微扰理论状态方程计算电解质水溶液的活度系数
被引：20
作者：
李春喜
宋红燕
李以圭
陆九芳
机构：
[1] 北京化工大学化学工程学院!北京,北京化工大学应用化学系!北京,清华大学化学工程系!北京,清华大学化学工程系!北京
来源：
关键词：
微扰理论;
势能函数;
电解质溶液;
状态方程;
活度系数;
D O I：
暂无
中图分类号：
O646.1 [电解质溶液理论];
学科分类号：
070306 [物理化学（含化学物理）];
摘要：
An equation of state for electrolyte aqueous solution is developed by treating the ion-ion electrostatic and ion-solvent molecule interactions with primitive MSA and perturbation theory, respectively. The effect of the dielectric constant on the ionic chemical potential and the calculation accuracy of ionic mean activity coefficients for 2∶1 and 1∶1 type halide aqueous solution are discussed.By taking ionic Pauling diameter as ionic hard sphere diameter for anions and treating the cation hard sphere diameter as ionic strength dependent, the equation can be used to calculate ionic activity coefficients in the moderate concentration range with good accuracy.
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页码：363 / 367
页数：5
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