Pitzer混合参数对HCl-NaCl-H2O体系溶解度预测的影响

被引：7

作者：

李亚红

高世扬

宋彭生

夏树屏

机构：

[1] 西北大学化学系!西安,国科学院青海盐湖研究所!西宁,国科学院青海盐湖研究所!西宁,国科学院青海盐湖研究所!西宁

来源：

物理化学学报 | 2001年 / 01期

关键词：

Pitzer混合参数; 活度系数; 溶解度预测;

D O I：

暂无

中图分类号：

O642 [化学热力学、热化学、热力学平衡]; O646.1 [电解质溶液理论];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reports the results of solubility calculation of the phase system HCl- NaCl- H2O at 25℃ whenθ HNa (interactions of two species with the same charge) andΨ HNaCl (interactions of three species) were changed by＋ 10％ and－ 10％ . The results indicated that the effects of the two kinds of interactions on the calculated solubility of the system were regular. The calculated solubilities of the system did not vary while the two interactions were increased and decreased simultaneously. The solubility data of the system changed greatly as one interaction was increased and the other decreased. This study is significant for the chemical technology of salting out salts from the water- salt system.

引用

页码：91 / 94

页数：4

共 4 条

[1] 碱金属氯化物-盐酸-水体系25℃溶解度预测 [J].