半夏的化学成分研究

被引:42
作者
杨虹
侴桂新
王峥涛
胡之璧
机构
[1] 中药标准化教育部重点实验室
关键词
半夏; 化学成分;
D O I
暂无
中图分类号
R284.1 [化学分析与鉴定];
学科分类号
摘要
目的研究半夏的化学成分。方法采用硅胶柱及SephadaxLH-20凝胶柱色谱法,运用波谱方法确定结构。结果从半夏中分离得到15个化合物,分别为大黄酚(1),丁二酸(2),正十六碳酸-1-甘油酯(3),soyacerebrosideI(4),octadeca-9,12-dienoicacidethylester(5),monogalactosyldiacyglycerol(6),soyacerebrosideII(7),3-O-(6′-O-棕榈酰基-β-D-吡喃葡萄糖基)豆甾-5-烯(8),对二羟基苯酚(9),1,6:3,4-dianhydro-β-D-allosep(10),1,6:2,3-dianhydro-β-D-allosep(11),5-羟甲基糠醛(12),邻二羟基苯酚(13)及β-谷甾醇(14),胡萝卜苷(15)。结论化合物1,3,5,6,811,13均为首次从半夏中分离得到。
引用
收藏
页码:99 / 101
页数:3
相关论文
共 7 条
[1]  
NMR study of some anthraquinones from Rhubarb. DANIELSEN K,,EKSENS D W,FRANCIS G W. Magnetic Resonance in Chemistry . 1992
[2]  
Analysis of molecular species of glycolipids in fruit pastes of red bell pepper by high-performance liquid chromatography-mass spectrometry. RYO Y,,KOICHI A,TAKAHIRO I,et al. J Ag-ric Food Chem . 2001
[3]  
Studies on the chemical constit-uents ofEuphorbia mandshuricaMaxim. JIAO Y,,YUANC L,YANG S S. Chin Tradit Herb Drugs(中草药) . 1990
[4]  
Carbon-13NMR studies on catechol,phenol and benzene derivatives of biological rele-vance. ADOLFO L,,MAURA M,GIUSEPPE S. Magnetic Resonance in Chemistry . 1985
[5]  
13C-NMR study of1,6:2,3-and1,6:3,4-dianhydro-β-D-hexopyranoses and their O-acetyl and de-oxy derivatives. TOMAS T,,MILOSLAV C A. Carbohydrate Research . 1979
[6]  
Cytotoxic polyisoprenes and glycosides of long-chain fatty alcohols fromDi-mocarpus fumatus. VOUTQUENNE L,,LAVAUD C,MASSIOT G,et al. Phytochemistry . 1999
[7]  
Sphingo-lipids and glycerolipids I.Chemical structures and Ionophoretic activities of soyacerebrosides I and II from soybean. SHIBUYA H,,KAWASHIMA K,SAKAGAMI M,et al. Chemical and Pharmaceutical Bulletin . 1990