ApplicationofannexationprincipletothestudyofthermodynamicpropertiesofternarymoltensaltsCaCl2-MgC2-NaCl

被引:12
作者
ZHANG Jian Metallurgical Engineering School University of Science and Technology Beijing Beijing China [100083 ]
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中图分类号
O611 [化学元素与无机化合物];
学科分类号
070301 [无机化学];
摘要
<正> Based on the practical basis of measured activities and phase diagrams as well as in the light of the mass action law, the model of inseparable cations and anions of molten salts and mattes, and the annexation principle of two kinds of solutions in binary melts, the calculating model of mass action concentrations of molten salts CaCl2-MgCl2-NaCl was formulated. The results of calculation not only agree with experimental values, but also obey the mass action law, testifying that the model formulated can embody the structural characteristics of these ternary salts, and that the model of inseparable cations and anions as well as the annexation principle of two kinds of solutions in binary melts are also appficable to these ternary salts.
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页码:209 / 213
页数:5
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