用八羰基合二钴在相转移催化条件下合成1-萘乙酸

被引：6

作者：

戴金水

机构：

[1] 北京防化指挥工程学院化学教研室!北京

来源：

应用化学 | 1998年 / 01期

关键词：

萘乙酸; 合成; 氯甲基萘; 相转移催化; 八羰基合二钴;

D O I：

暂无

中图分类号：

O643 [化学动力学、催化作用];

学科分类号：

070304 ; 081704 ;

摘要：

1-Naphthalene acetic acid was synthesized from 1-chloromethyl naphthalene byoctacarbonyl dicobalt under phase transfer catalytic conditions. Conversion was 99% andyield 83%. The effects of reaction temperatures, ratios of reactants, solvents, contents ofcatalyst and concentration of alkali on conversion have been investigated. Among the phasetransfer catalysts tested, the most effective was hexadecyltrimethylammonium chloride.

引用

页码：86 / 88

页数：3