小刺猴头菌子实体水溶性多糖HPⅠ的结构研究

被引:16
作者
王昭晶
梁忠岩
罗巅辉
机构
[1] 东北师范大学生命科学学院,东北师范大学生命科学学院,东北师范大学生命科学学院长春,华侨大学材料科学与工程学院,泉州,长春,长春,华侨大学材料科学与工程学院,泉州
关键词
小刺猴头菌子实体; 多糖; 结构研究;
D O I
暂无
中图分类号
R284 [中药化学];
学科分类号
100804 [中药化学];
摘要
A water soluble polysaccharide (HPⅠ) was isolated from the Hericium caput-medusae and examined homogenously by Sephadex G-100 column chromatography,cellulose acetate film electrophoresis and specific optical rotation measurement. This HPⅠconsists of Fuc,Glc and Gal in the molar ratios of 0.423∶1∶2.110. Its structural features were investigated by methylation and GC-MS analysis,periodate oxidation-Smith degradation,and partial acid-hydrolysis. In addition, enzymatic degradation experiments and GC analysis were applied. The following structure of the highly branched repeating unit was established: 6→)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→6)-Gal-(1→ 2 ↑ 1 2 ↑ 1 2 ↑ 1 Gal-(1→4)-Fuc Glc-(1→3)-Glc 2 Gal-(1→6)-Glc 3 The activities of HPⅠwere tested in mice. All the samples exhibited high effect of prevention and cure against chronic gastricism.
引用
收藏
页码:1474 / 1476
页数:3
相关论文
共 1 条
[1]
斜顶菌中水溶性多糖的研究(Ⅰ)——分离、纯化与结构确定 [J].
梁忠岩 ;
张翼伸 .
高等学校化学学报, 1983, (03) :364-370