土壤和沉积物中的聚合有机质对多环芳烃分布和提取的影响

被引：7

作者：

冉勇 ^{[1
]}

孙可 ^{[1
]}

马晓轩 ^{[1
]}

王国辉 ^{[2
]}

Peter Grathwohl ^{[2
]}

曾永平 ^{[1
]}

机构：

[1] 中国科学院广州地球化学研究所有机地球化学国家重点实验室

[2] Center of Applied Geosciences,University of

来源：

生态毒理学报 | 2006年 / 04期

关键词：

非水解有机碳; 碳黑; 多环芳烃; 加速溶剂提取; 土壤; 沉积物;

D O I：

暂无

中图分类号：

X53 [土壤污染及其防治];

学科分类号：

082803 ; 120405 ;

摘要：

为了研究土壤和沉积物中凝聚型有机碳(碳黑、干酪根)的含量及其对多环芳烃(PAHs)分布和提取的影响,分别用三氟醋酸(TFA)和在375℃下通氧燃烧的方法从珠江三角洲2个污染土壤和5个河口沉积物样品中提取酸非水解有机碳(NHC)和碳黑(BC);用索氏抽提法和不同溶剂的加速溶剂萃取法(包括连续加速萃取法ASESum和标准溶剂萃取法ASESTD)抽提土壤和沉积物中的多环芳烃,并在不同温度梯度(25℃到150℃)下用水为溶剂加速溶剂萃取其水溶态.结果表明,1)NHC是珠江三角洲土壤和沉积物中总有机碳的重要组成部分,NHC碳明显高于BC碳,NHC和BC分别占土壤和沉积物中有机碳的25.6%￣73.8%和4.64%￣17.3%.2)3种有机溶剂(丙酮、甲苯1、甲苯2)连续抽提的PAHs含量是索氏抽提的2.11倍;5种ASE方法(丙酮、甲苯1、甲苯2、ASESum、ASESTD)提取的PAHs含量与NHC含量存在明显的相关性,而且比PAHs含量与BC或无定型有机碳(AOC)含量的相关性更明显.3)在不同温度梯度下水溶态PAHs浓度符合Van’tHoff方程.研究说明除了BC外,非水解有机碳对土壤和沉积物中PAHs的分布和提取具有重要影响.

引用

页码：336 / 342

页数：7

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