高性能钯膜及其在氨分解制氢中的应用

被引：4

作者：

王晓光 ^{[1
]}

韦永德 ^{[1
]}

张建 ^{[2
]}

侯守福 ^{[2
]}

徐恒泳 ^{[2
]}

李文钊 ^{[2
]}

机构：

[1] 哈尔滨工业大学应用化学系

[2] 中国科学院大连化学物理研究所

来源：

化工学报 | 2006年 / 12期

关键词：

钯膜; 氨分解; 现场制氢; 膜分离;

D O I：

暂无

中图分类号：

TQ116.2 [氢气];

学科分类号：

0817 ;

摘要：

A high-performance Pd membrane for H2 separation was prepared by the modified electroless plating method.In order to obtain pure H2 for fuel cell use,the NH3 cracker was integrated with a Pd membrane-based purifier and the permeation performance of Pd membrane （H2 flux, recovery yield and purity）was investigated at 510℃ and a pressure range from 0.1 MPa to 0.5 MPa.High separation efficiency was achieved with such an intergrated system.A 75 cm3·cm~ -2 ·min~ -1 H2 flow with purity as high as 99.93% could be obtained.Throughout a 120 h stability test, the H2 flux and recovery yield were maintained at 63 cm3·cm~ -2 ·min~ -1 and 85% respectively.

引用

页码：2897 / 2901

页数：5