高硅MCM-22分子筛的合成及其C4烯烃裂解性能

被引:22
作者
赵国良
滕加伟
许宁
唐颐
谢在库
杨为民
陈庆龄
机构
[1] 复旦大学化学系,上海石油化工研究院,复旦大学化学系,复旦大学化学系,上海石油化工研究院,上海石油化工研究院,上海石油化工研究院上海上海石油化工研究院,上海,上海,上海上海石油化工研究院,上海,上海,上海,上海,上海
关键词
催化裂解; MCM-22; C4烯烃; 丙烯;
D O I
暂无
中图分类号
TQ221.21 [];
学科分类号
摘要
MCM-22 zeolite with a high SiO2/Al2O3 ratio was synthesized in the hydrothermal system of Na2O-SiO2-Al2O3-(CH2)6NH and its catalytic performance in the C4-olefins cracking reaction was investigated. It was found that MCM-22 showed an excellent catalytic performance on C4-olefins cracking reaction to produce propylene. The results indicated that high temperature and high LHSV(liquid hourly space velocity) were favorable for the production of propylene with a high selectivity. Lifetime test of HMCM-22 and HZSM-5 for the cracking of C4 olefins indicates that the deactivation rate of HMCM-22 is lower than that of HZSM-5.
引用
收藏
页码:1140 / 1142
页数:3
相关论文
共 3 条
[1]
烯烃催化裂解增产丙烯催化剂 [J].
滕加伟 ;
赵国良 ;
谢在库 ;
杨为民 .
石油化工, 2004, (02) :100-103
[2]
P改性HZSM-5分子筛上C_4 烯烃裂解性能研究(英文).[J].赵国良;滕加伟;金文清;杨为民;谢在库;陈庆龄.催化学报.2004, 01
[3]
AlSi-ZSM-48沸石分子筛的合成及其催化性能 [J].
赵国良 ;
滕加伟 ;
宋庆英 ;
谢在库 ;
陈庆龄 .
催化学报, 2003, (02) :119-122