Y掺杂Ba0.90Sr0.08Ca0.02TiO3固溶体纳米晶粒尺寸对其晶体结构的影响

被引:2
作者
李东升
吴淑荣
熊为淼
王文亮
杨文选
机构
[1] 延安大学化学系
[2] 化学反应工程省级重点实验室!延安
[3] 西北大学化学系!西安
关键词
Ba0.90Sr0.08Ca0.02TiO3固溶体; 纳米晶粒尺寸; 钇掺杂; 晶体结构;
D O I
暂无
中图分类号
O76 [晶体结构];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title nanocrystalline powders were prepared by sol-gel method, the influences of grain size on crystal structure were investigated by XRD and DSC techniques. The experiment results show that the tetragonal ferroelectric phase content of the powders and the Curie temperature Tc are increased with the increase of grain size. When the grain size is less than 34. 7nm, crystal structure of the particle changes into cubic paraelectric phase and the transition of ferro-paraelectric phase disappears as well.
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页码:519 / 522
页数:4
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