双酚A分子印迹聚合物的制备和识别性能研究

被引:9
作者
赵美萍
李元宗
张新祥
常文保
机构
[1] 生物有机分子工程教育部重点实验室
[2] 北京大学化学与分子工程学院化学生物学系
关键词
双酚A; 分子印迹聚合物; 识别性质;
D O I
暂无
中图分类号
O657.7 [色谱分析];
学科分类号
摘要
A molecular imprinted polymer of bisphenol A(P BPA) was prepared. The eluting efficiencies of different solvent systems for eliminating the template from the P BPA were investigated. The P BPA showed specific recognition characteristics for molecules with a bisphenolic structure such as bisphenol A, 4,4-bis(4-hydroxyphenyl)valeric acid and phenolphthalein. The possibility to use bisphenol A-imprinted polymer as a solid-phase extraction material was also studied. The best binding buffer was found to be acetonitrile containing 0.05%(volume fraction) of Tween 20, and acetonitrile-ethanol solution containing 0.5%(volume fraction) diethanolamine was found to be the optimal eluting solvent.
引用
收藏
页码:1204 / 1206
页数:3
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