Effects of rapid quenching on microstructures and electrochemical properties of La0.7Mg0.3Ni2.55Co0.45Bx(x=0-0.2) hydrogen storage alloy

被引：3

作者：

张羊换 ^{[1
]}

董小平 ^{[2
]}

王国清 ^{[3
]}

郭世海 ^{[3
]}

任江远 ^{[2
]}

王新林 ^{[3
]}

机构：

[1] School of Material, Inner Mongolia University of Science and Technology, Baotou 014010, China Department of Functional Material Research, Central I ron and Steel Research Institute, Beijing 100081, China

来源：

TransactionsofNonferrousMetalsSocietyofChina | 2006年 / 04期

基金：

中国国家自然科学基金;

关键词：

La-Mg-Ni based electrode alloys; rapid quenching; microstructures; electrochemical properties;

D O I：

暂无

中图分类号：

TG156.3 [淬火、表面淬火];

学科分类号：

080201 ; 080503 ;

摘要：

In order to improve the electrochemical performances of La-Mg-Ni based electrode alloys with PuNi3-type structure, a trace of boron was added in La0.7Mg0.3Ni2.55Co0.45 alloy. The La0.7Mg0.3Ni2.55Co0.45Bx(x=0, 0.05, 0.1, 0.15 and 0.2) alloys were prepared by casting and rapid quenching. The electrochemical performances and microstructures of the as-cast and quenched alloys were investigated. The effects of rapid quenching on the microstructures and electrochemical performances of the above alloys were investigated. The results show that the as-cast and quenched alloys are composed of (La, Mg)Ni3 phase, LaNi5 phase and LaNi2 phase. A trace of the Ni2B phase exists in the as-cast alloys containing boron, and the Ni2B phase in the B-contained alloys nearly disappears after rapid quenching. Rapid quenching increases the amount of the LaNi2 phase in the B-free alloy, but it decreases the amount of the LaNi2 phase in the boron-containing alloys. The effects of rapid quenching on the capacities of the boron-containing and boron-free alloys are different. The capacity of the B-free alloy monotonously decreases with increasing quenching rate, whereas the capacities of the B-contained alloys have a maximum value with the change of the quenching rate. The rapid quenching can improve the stability of La-Mg-Ni based electrode alloy but lowers the discharge plateau voltage and decreases the plateau length. The effect of rapid quenching on the activation capabilities of the alloys was complicated.

引用

页码：800 / 807

页数：8