苯醚甲环唑在芹菜及其土壤中的残留测定和消解动态研究

被引：21

作者：

初春 ^{[1
]}

王志华 ^{[1
]}

秦冬梅 ^{[2
]}

龚勇 ^{[2
]}

季颖 ^{[2
]}

机构：

[1] 化工资源有效利用国家重点实验室北京化工大学理学院

[2] 农业部农药检定所

来源：

中国科学:化学 | 2011年 / 41卷 / 01期

关键词：

苯醚甲环唑; 消解动态; 残留; 水解; 半衰期;

D O I：

暂无

中图分类号：

S481.8 [];

学科分类号：

090403 ;

摘要：

采用气相色谱-电子捕获检测,对芹菜及其土壤中的苯醚甲环唑消解动态和最终残留量进行了研究,评价了苯醚甲环唑在芹菜上使用后的残留行为和环境安全性.苯醚甲环唑在芹菜及土壤中的残留消解动态均符合一级动力学方程,苯醚甲环唑在芹菜上消解快;苯醚甲环唑最终残留量与施药的剂量、施药次数及采样的间隔时间有关;水解研究表明,苯醚甲环唑是稳定的农药,在不同温度和不同pH的研究条件下水解半衰期均大于166d,碱性条件更有利于苯醚甲环唑的降解.

引用

页码：129 / 135

页数：7

共 12 条

[1]

Determination and dynamics of difenoconazole residues in Chinese cabbage and soil[J]. Zhi Hua Wang~(a,*)Tong Yang~a Dong Mei Qin~b Yong Gong~b Ying Ji~b a State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China b Institute for the Control of Agrochemicals,Ministry of Agriculture,People’s Republic of China,Beijing 100026,China.Chinese Chemical Letters. 2008(08)

[2]

Pyrethroid insecticides: Isoform-dependent hydrolysis, induction of cytochrome P450 3A4 and evidence on the involvement of the pregnane X receptor[J] . Dongfang Yang,Xiliang Wang,Yi-tzai Chen,Ruitang Deng,Bingfang Yan.Toxicology and Applied Pharmacology . 2009 (1)

[3] Captan residue reduction in apples as a result of rinsing and peeling [J].

Rawn, Dorothea F. K. ;

Quade, Sue C. ;

Sun, Wing-Fung ;

Fouguet, Andre ;

Belanger, Andre ;

Smith, Mark .

FOOD CHEMISTRY, 2008, 109 (04) :790-796

[4]

Degradation of the fungicide carbendazim in aqueous solutions with UV/TiO 2 process: Optimization, kinetics and toxicity studies[J] . J. Saien,S. Khezrianjoo.Journal of Hazardous Materials . 2008 (2)

[5]

Degradation kinetics and safety evaluation of tetraconazole and difenoconazole residues in grape[J] . KaushikBanerjee,Dasharath POulkar,Sangram HPatil,SomaDasgupta,Pandurang GAdsule.Pest. Manag. Sci. . 2008 (3)

[6]

Sample preparation techniques for the determination of trace residues and contaminants in foods[J] . Kathy Ridgway,Sam P.D. Lalljie,Roger M. Smith.Journal of Chromatography A . 2007 (1)

[7] Determination of thiophanate methyl and carbendazim residues in vegetable samples using microwave-assisted extraction [J].

Singh, Shashi B. ;

Foster, Gregory D. ;

Khan, Shaharnat U. .

JOURNAL OF CHROMATOGRAPHY A, 2007, 1148 (02) :152-157

[8] Effect of propiconazole and difenoconazole on the control of anthracnose of chilli fruits caused by Colletotrichum capsici [J].

Gopinath, K. ;

Radhakrishnan, N. V. ;

Jayaraj, J. .

CROP PROTECTION, 2006, 25 (09) :1024-1031

[9] Recent applications of sample preparation techniques in food analysis [J].

Buldini, PL ;

Ricci, L ;

Sharma, JL .

JOURNAL OF CHROMATOGRAPHY A, 2002, 975 (01) :47-70

[10]

Effects of azoxystrobin, difenoconazole, polyoxin B (polar) and trifloxystrobin on germination and growth of Alternaria alternata and decay in red delicious apple fruit[J] . Moshe Reuveni,Dimitri Sheglov.Crop Protection . 2002 (10)

← 1 2 →