Wien Effect in Suspensions of Electrodialyzed Soil Particles and Its Influencing Factors

<正>The electrical conductivity of suspensions and their supernatants from the electrodialyzed clay fractions of latosol, yellow-brown soil and black soil equilibrated with nitrate solutions were determined at different field strengths using a short high-voltage pulse apparatus to demonstrate the Wien effect in soil suspensions and to investigate factors affecting it. It was found that Wien effect was much stronger in suspensions with a clay content of 30 g kg-1 from the soils equilibrated with a 1 × 10-4 KNO3 solution than in their supernatants. The threshold field strength (TFS), at which the relative conductivity is equal to 1.05, i.e., the Wien effect begins to be obvious, of the yellow-brown soil suspensions (clay content of 30 g kg-1) equilibrated with different nitrate solutions of a concentration of 1 × 10-4/z mol L-1 , where z is the valence, varied with the type of nitrates, being lowest for NaNO3 (47 kV cm-1) and highest for Ca(NO3)2 (98 kV cm-1). At high field strengths (larger than 130 kV cm-1