Synthesis,structure and magnetic properties of manganese(Ⅱ)coordination polymer with azido and zwitterionic dicarboxylate ligand

被引：5

作者：

Rong-Mei Wen

Song-De Han

Hao Wang

Ying-Hui Zhang

机构：

[1] DepartmentofChemistry,TianjinKeyLaboratoryofMetalandMolecule-basedMaterialChemistry,andKeyLaboratoryofAdvancedEnergyMaterialsChemistry(MOE),NankaiUniversity

来源：

Chinese Chemical Letters | 2014年 / 25卷 / 06期

关键词：

Manganese(Ⅱ); Azido anion; Magnetism; 1,4-Bis(pyridinil-3-carboxylato)-1,4-; dimethylbenzene;

D O I：

暂无

中图分类号：

O627.7 [第Ⅶ族元素有机化合物（卤素除外）];

学科分类号：

070303 ; 081704 ;

摘要：

A coordination polymer formulated as([Mn2L（N3）4]-2H2O}_n（1）(L= 1,4-bis（pyridinil-3-carboxylato）-l,4-dimethylbenzene]was synthesized and structurally and magnetically characterized.The uniform Mn（II）chains with mixed（μ-EO-N3）2（μ-COO） triple bridges（EO = end-on） are linked by L ligands to generate a2-fold interpenetrating 3D framework.Meanwhile,magnetism analysis reveals antiferromagnetic coupling for 1.

引用

页码：854 / 858

页数：5

共 2 条

[1]

A new 8-connected self-penetrating metal-organic framework based on dinuclear cadmium clusters as secondary building units[J]. Kun-Huan He,Yun-Wu Li,Yong-Qiang Chen,Ze Chang.Chinese Chemical Letters. 2013(08)

[2] Synthesis and Structural Characterization of a New Cadmium(II) Complex with a Double Betaine [J].

ZHENG FaKuna WU AQinga b LI Yana b GUO GuoConga HUANG JinShuna a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China b Graduate School The Chinese Academy of Sciences Beijing China .

结构化学, 2005, (08) :940-944+862

← 1 →