活性炭负载钌基氨合成催化剂的制备和催化活性

被引：42

作者：

王晓南

朱虹

夏伟琴

刘化章

机构：

[1] 浙江工业大学催化研究所!杭州,浙江工业大学催化研究所!杭州,浙江工业大学催化研究所!杭州,浙江工业大学催化研究所!杭州

来源：

催化学报 | 2000年 / 03期

关键词：

钌; 活性炭; 负载型催化剂; 氨合成;

D O I：

暂无

中图分类号：

O643 [化学动力学、催化作用];

学科分类号：

摘要：

A series of active carbon supported ruthenium based catalysts, promoted by alkali and alkaline earth nitrate, are prepared by impregnation method and with RuCl 3·3H 2O as precursor. Effects of support, promoter and preparation conditions on catalytic activity are discussed. The catalytic activity is evaluated with a fixed bed micro reactor at lower pressure. The results show that the impregnation sequence affects the catalytic activity obviously. Ba Ru K/C is the preferred impregnation sequence. And effects of nature, producing area and pre treatment of the support on catalytic activity are also examined. Catalytic activity increases with the amount of Ru deposited on the support, it attains maximum when Ru loading is 8%. Optimal molar ratio of promoter to Ru is 10.

引用

页码：276 / 278

页数：3