氨基封端苯胺五聚体的合成及紫外光谱研究

被引：3

作者：

陈梁

于有海

毛华平

卢晓峰

张万金

危岩

机构：

[1] 吉林大学麦克德尔米德实验室

[2] Department of Chemistry

[3] Drexel University

[4] PA

[5] USA 长春

[6] 长春

来源：

高等学校化学学报 | 2004年 / 09期

关键词：

苯胺齐聚物; 氨基封端苯胺五聚体; 紫外可见光谱;

D O I：

暂无

中图分类号：

O657.3 [光化学分析法（光谱分析法）];

学科分类号：

070302 ; 081704 ;

摘要：

Compound B was synthesized through oxidative coupling reaction of p-phenylene-diamine and compound A(acetylamino-capped aniline dimer). This synthetic route protected the N-phenyl-1,4-phenylenediamine from further reaction. The pentamer was synthesized by the hydrolysis of compound B(acetylamino-capped aniline pentamer) and was characterized by IR, elemental analysis and MALDI-TOF-MS. The chemical oxidation process of the pentamer was studied by UV-Vis spectra. It was found the pentamer was oxidized to its EB form and then to the pernigraniline oxidation state.

引用

页码：1768 / 1770

页数：3

共 4 条

[1] 母体苯胺六聚体的一步法合成及紫外光谱研究 [J].