超声波处理难降解有机物影响参数研究

被引:13
作者
张光明
周吉全
张锡辉
吴敏生
机构
[1] 清华大学深圳研究生院
[2] 清华大学深圳研究生院 深圳
[3] 深圳
关键词
超声波; 多氯联苯; 溴苯; 自由基清除剂;
D O I
暂无
中图分类号
X703.1 [技术方法];
学科分类号
083002 ;
摘要
考察了多种操作参数对多氯联苯、溴苯超声波降解的影响。结果表明,高频率、高声强、高流速、混合气体可以提高超声反应速率, 358kHz下降解速率比20kHz提高了848%, 34mL/min流速下比4 4mL/min提高了140%,参入Ar比单纯使用O2 提高83% ( +80%Ar)或66% ( +50%Ar)。然而高声强也造成了较多的能量消耗。自由基清除剂的存在则较大地降低了超声反应速率, 200mmol/LCO2- 存在时反应速率下降了79%。
引用
收藏
页码:42 / 45
页数:4
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